The control of crystal morphology is crucial to preparation of α-hemihydrate gypsum (α-HH). α-HH was prepared from phosphogypsum (PG) in Na 2 SO 4 solution at different temperatures. The effect of maleic acid (C 4 H 4 O 4) on the dehydration rate and growth behavior of α-HH was investigated by X-ray diffraction (XRD) and scanning …
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WhatsApp: +86 182217550731. Introduction. Gypsum is a material in which the amount of water of crystallization varies with its surrounding conditions, such as temperature or humidity, and can be classified into three groups, namely, calcium sulfate anhydrite (CaSO 4), calcium sulfate hemihydrate (CaSO 4 ∙1/2H 2 O), and calcium sulfate dihydrate (CaSO 4 ∙2H 2 …
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WhatsApp: +86 18221755073Preparation of α-hemihydrate gypsum crystal is an approach for utilization of phosphogypsum (PG), but the soluble phosphorus impurities in PG have a crucial influence on the performance of α-hemihydrate gypsum. In this article, different forms of soluble phosphorus (H3PO4, H2PO4− and HPO42−) on the setting time and mechanical …
WhatsApp: +86 18221755073This powder is led towards evaporation of most of its content of water and carbon dioxide to be converted to Calcium Sulfate Hemihydrate (also known as Plaster of Paris). Plaster …
WhatsApp: +86 18221755073gypsum (CaSO4 2H2O), hemihydrate gypsum (CaSO4 0.5H2O), and anhydrite (CaSO4) [1–3]. Phosphogypsum (PG) is mainly composed of calcium sulfate dihydrate (DH), which is a byproduct from the wet ...
WhatsApp: +86 18221755073The effects of phosphoric acid (H3PO4) in pressurized aqueous solution on the dehydration of CaSO4·2H2O to form α-hemihydrate gypsum (α-HH) phase and the regulation of crystal shape …
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WhatsApp: +86 18221755073In this study, phosphogypsum (PG) is simulated by doping fluorine and phosphorus ions in an analytically pure reagent of gypsum dihydrate. The influence of fluorine and phosphorus impurity and content on the dehydration reaction process of phosphogypsum and its crystalline micromorphology is assessed during the preparation …
WhatsApp: +86 18221755073The FGD gypsum produced from Xiaoshan Power Plant (Zhejiang Province, China) was adopted as raw material. The chemical composition is presented in Table 1. FGD gypsum is mainly composed of DH, with a purity of 94.23%. Some traces of heavy metals, 1.3 mg kg −1 Hg and 6.3 mg kg −1 Cr, are found in the FGD gypsum.
WhatsApp: +86 18221755073DOI: 10.1016/J.PCRYSGROW.2007.01.002 Corpus ID: 96747728; Calcium sulphate hemihydrate hydration leading to gypsum crystallization @article{Singh2007CalciumSH, title={Calcium sulphate hemihydrate hydration leading to gypsum crystallization}, author={Nakshatra Bahadur Singh and Bernhard Middendorf}, journal={Progress in …
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WhatsApp: +86 18221755073This work develops a new class of salt solution method to prepare alpha-calcium sulfate hemihydrate (α-HH) from flue gas desulfurization (FGD) gypsum in trace K 2 SO 4-contained 4.0 M Ca(NO 3) 2 aqueous solution at 95 °C under atmospheric pressure. The driving force for the phase transition is provided by the concentrated Ca(NO 3) 2 …
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WhatsApp: +86 18221755073Keywords: α-calcium sulfate hemihydrate, industrial by-product gypsum, FGD gypsum, phosphogypsum, preparation method 1. Introduction 1.1. α-calcium sulfate hemihydrate Calcium sulfate hemihydrate generally exists in two forms, i.e., α- and β-forms. As an important building material, the industrial production and application of β-form began ...
WhatsApp: +86 18221755073The bonding nature of water in gypsum, CaSO4·2H2O, and hemihydrate, CaSO4·1/2H2O, was suggested by characteristic absorption bands of water and sulphate ions.
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WhatsApp: +86 18221755073The fluidity of hemihydrate gypsum - PCE systems with different F − content is shown in Fig. 5.It was found that in all experiments, regardless of adding PCE or not, F − had a negative effect on the fluidity. This negative effect became more significant as the dosages of F − and PCE increased, while without PCE, it seemed very slight. When the …
WhatsApp: +86 18221755073thermal analysis in a sample of hemihydrate prepared by calcining gypsum under conditions simulating the manufacture of gypsum plaster in a kettle. By means of differential thermal analysis it is ...
WhatsApp: +86 18221755073A readily monitored and controllable hydrothermal system for the facile, cost-effective transformation of FGD gypsum to calcium sulfate hemihydrate whiskers. Particuology (2021) H. Fu et al. Role and fate of the lead during the conversion of calcium sulfate dihydrate to α-hemihydrate whiskers in ethylene glycol-water solutions.
WhatsApp: +86 18221755073DOI: 10.1016/j.conbuildmat.2023.130453 Corpus ID: 256217243; Utilization of phosphogypsum to synthesize α-hemihydrate gypsum in H3PO4–H2O solution @article{Chen2023UtilizationOP, title={Utilization of phosphogypsum to synthesize $alpha$-hemihydrate gypsum in H3PO4–H2O solution}, author={Long Chen and Lin …
WhatsApp: +86 18221755073Gypsum (calcium sulfate dihydrate) is one of the most used inorganic binding materials in the world. During calcination, calcium sulfate subhydrates are formed and, for technical reasons, are mixed with water …
WhatsApp: +86 18221755073DOI: 10.1016/j.jcrysgro.2021.126360 Corpus ID: 241731164; Preparation of hemihydrate gypsum with controllable morphology in Glycerol-NaCl-Water solutions with maleic acid @article{Chen2021PreparationOH, title={Preparation of hemihydrate gypsum with controllable morphology in Glycerol-NaCl-Water solutions with maleic acid}, …
WhatsApp: +86 18221755073The massive accumulation of flue gas desulfurization (FGD) gypsum produced in the wet limestone-gypsum flue gas desulfurization process not only encroaches on lands but also causes serious environmental pollution. The preparation of α-hemihydrate gypsum (α-HH) is an important way to achieve high-value utilization of …
WhatsApp: +86 18221755073DOI: 10.1016/j.conbuildmat.2024.136656 Corpus ID: 269855858; Preparation of α-calcium sulfate hemihydrate with high mechanical strength from natural fibrous gypsum in KCl-mediated glycerol-water solution
WhatsApp: +86 18221755073Lime pretreated phosphogypsum(PG) was calcined at 500 °C to produce anhydrate gypsum cement. Due to the slow hydration of anhydrate gypsum, additives, K2SO4 and hemihydrate gypsum were selected to accelerate the hydration of anhydrate. The hydration characteristics, the resistance to hydrodynamic water, and the …
WhatsApp: +86 18221755073When gypsum is dissolved in the solution, a supersaturated solution to α-HH is developed since its supersaturation is lower than that of gypsum at the temperature range of 85–100 °C (Li and Demopoulos, 2006; Fu et al., 2012), and a spontaneous phase transformation from gypsum into α-HH proceeds simultaneously with arsenate …
WhatsApp: +86 18221755073These are expected to be α-hemihydrate. This theory of the formation of α-hemihydrate inside of a gypsum crystal is experimentally proven in the present work. This work firstly shows that the ...
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